The Provincial Superior is assisted by four Councillors. They are appointed by the Superior General with the consent of her Council, after prior consultation with the sisters in the Province, according to the norms given in the Directory of the Ursulines of Mary Immaculate. One of the Councillors is the Vice Provincial.
The Provincial Superior with the consent of her Council appoints the Provincial Secretary and the Provincial Treasurer.
2010 – 2013
| Sr. Gaudenzia Chunayanmackal | Provincial Superior |
| Sr. Kusum Panthalanickal | Vice Provincial |
| Sr. Lucien Kochuparambil | Councillor |
| Sr. Ruzaria Corte | Councillor |
| Sr. Celine Jose Thuruthippallil | Councillor and Secretary (2010 – 2011) |
| Sr. Nikesh Mecherithakadiel | Treasurer |
| Sr. Archana Souza | Secretary (2011 – 2013) |
2007 – 2010
| Sr. Berchmans Kuzhimattathil | Provincial Superior |
| Sr. Calista Pulakudiyil | Vice Provincial |
| Sr. Angeline Maliakkal | Councillor |
| Sr. Sally Joseph Puthenpurackal | Councillor |
| Sr. Fabian Kaviyil | Councillor |
| Sr. Nikesh Mecherithakadiel | Treasurer |
| Sr. Celine Jose Thuruthippallil | Secretary |
2004 – 2007
| Sr. Berchmans Kuzhimattathil | Provincial Superior |
| Sr. Christopher Nellanikkatt | Vice Provincial |
| Sr. Angeline Maliakkal | Councillor |
| Sr. Nives D’Souza | Councillor |
| Sr. Kusum Panthalanickal | Councillor |
| Sr. Jaya Kunnel | Treasurer and Secretary |
2001 – 2004
| Sr. Vandana Fernandes | Provincial Superior |
| Sr. Berchmans Kuzhimattathil | Vice Provincial |
| Sr. Calista Pulakudiyil | Councillor |
| Sr. Christopher Nellanikkatt | Councillor |
| Sr. Kusum Panthalanickal | Councillor |
| Sr. Jane Mary Kochukaroor | Treasurer |
| Sr. Pius Poranganal | Secretary |
1998 – 2001
| Sr. Vandana Fernandes | Provincial Superior |
| Sr. Berchmans Kuzhimattathil | Vice Provincial |
| Sr. Aquinas Parickappillil | Councillor |
| Sr. Linda Kochumuriyil | Councillor |
| Sr. Calista Pulakudiyil | Councillor |
| Sr. Jane Mary Kochukaroor | Treasurer |
| Sr. Pius Poranganal | Secretary |
1995 – 1998
| Sr. Gaudenzia Chunayanmackal | Provincial Superior |
| Sr. Vandana Fernandes | Vice Provincial |
| Sr. Geena Vengathanam | Councillor |
| Sr. Georgia Myladoor | Councillor |
| Sr. Aquinas Parickappillil | Councillor |
| Sr. Nikesh Mecherithakadiel | Treasurer and Secretary |
1991 – 1995
| Sr. Gaudenzia Chunayanmackal | Provincial Superior |
| Sr. Alphonsa Thyparambil | Vice Provincial |
| Sr. Berchmans Kuzhimattathil | Councillor |
| Sr. Geena Vengathanam | Councillor |
| Sr. Yvonne Lima Fernandes | Councillor |
| Sr. Nikesh Mecherithakadiel | Treasurer and Secretary |
1988 – 1991
| Mother Giovanna Alberoni | Provincial Superior |
| Sr. Elvira Mattappally | Vice Provincial |
| Sr. Bernardina Poonthottam | Councillor |
| Sr. Yvonne Lima Fernandes | Councillor |
| Sr. Berchmans Kuzhimattathil | Councillor |
| Sr. Sonia Palayikudiyil | Treasurer |
| Sr. Gonzaga Thuruthiyil | Secretary |
